[3+2]-cycloaddition of nonstabilized azomethine ylides. 10. An efficient strategy for the construction of x-azatricyclo[m.n.0.0(a,b)]alkanes by intramolecular cycloaddition of cyclic azomethine ylide

Authors
Pandey, G Sahoo, AK Bagul, TD
Citation
G. Pandey et al., [3+2]-cycloaddition of nonstabilized azomethine ylides. 10. An efficient strategy for the construction of x-azatricyclo[m.n.0.0(a,b)]alkanes by intramolecular cycloaddition of cyclic azomethine ylide, ORG LETT, 2(15), 2000, pp. 2299-2301
Citations number
38
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANIC LETTERS
ISSN journal
15237060 → ACNP
Volume
2
Issue
15
Year of publication
2000
Pages
2299 - 2301
Database
ISI
SICI code
1523-7060(20000727)2:15<2299:[ONAY1>2.0.ZU;2-7
Abstract
[GRAPHICS] Various new structural entities related to x-azatricyclo[m.n.0.0(a,b)]alkan es are constructed by the intramolecular [3 + 2] dipolar cycloaddition of n onstabilized cyclic azomethine ylides. The ylide is generated by the sequen tial double desilylation of N-alkyl alpha,alpha'-bis(trimethylsilyl)cyclic amines using Ag(I)F as a one-electron oxidant.