Suzuki cross-coupling reactions catalyzed by palladium nanoparticles in aqueous solution

Authors
Li, Y Hong, XM Collard, DM El-Sayed, MA
Citation
Y. Li et al., Suzuki cross-coupling reactions catalyzed by palladium nanoparticles in aqueous solution, ORG LETT, 2(15), 2000, pp. 2385-2388
Citations number
21
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANIC LETTERS
ISSN journal
15237060 → ACNP
Volume
2
Issue
15
Year of publication
2000
Pages
2385 - 2388
Database
ISI
SICI code
1523-7060(20000727)2:15<2385:SCRCBP>2.0.ZU;2-#
Abstract
[GRAPHICS] Palladium nanoparticles stabilized by poly(N-vinyl-2-pyrrolidone) (PVP) are efficient catalysts for the Suzuki reactions in aqueous medium. The time d ependence of the fluorescence intensity of the biphenyl product in the reac tion between iodobenzene and phenylboronic acid is used to determine the in itial rate of the catalytic reaction. The initial rate depends linearly on the concentration of Pd catalyst, suggesting that the catalytic reaction oc curs on the surface of the Pd nanoparticles.