Presently, coatings of electroless nickel are used for diamond turning mold
s for injection molding of optical lenses. We have investigated the diamond
machinability of substoichiometric hard nitride coatings (TiNx, TiAlNx. an
d CrNx). These coatings have a superior hardness compared to electroless ni
ckel suggesting an improved wear resistance of molds with optical surface q
uality. In the case of CrNx and TiAIN(x), high tool wear occurred, even aft
er small cutting distances, and the surfaces showed a roughness larger than
R-a = 0.5 mu m. A considerably higher surface quality was obtained on TiNx
coatings. The best results (R-a = 15 nm) were achieved with a nitrogen con
tent of x = 0.03. As a first application, a mold for a diffractive optical
element was machined using this newly developed substoichiometric titanium
nitride deposit. (C) 2000 Elsevier Science Inc. All rights reserved.