Citation
Vn. Plakhotnik et al., Effect of Li+ ions on the kinetics of the alkaline hydrolysis of difluorophosphate anion, RUSS J C CH, 26(7), 2000, pp. 470-472
Citations number
21
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY
ISSN journal
10703284
→ ACNP
Volume
26
Issue
7
Year of publication
2000
Pages
470 - 472
Database
ISI
SICI code
1070-3284(200007)26:7<470:EOLIOT>2.0.ZU;2-C
Abstract
The influence of the Li+ cation on the alkaline hydrolysis kinetics of a mi
xed-ligand fluoroacido complex was studied for the first time. The importan
t role of the dehydration of the reacting particles in ion pair formation w
as shown. Certain hypotheses on possible mechanisms of the ligand substitut
ions in PO2F2- in the presence of the Li+ ion were advanced.