Crystal structure of a supramolecular cluster adduct with cucurbituril, (H3O)(4)[W3S7Cl6](2)(C36N24O12H36)center dot 8H(2)O

Authors
Geras'ko, OA Virovets, AV Dybtsev, DN Klegg, V Fedin, VP
Citation
Oa. Geras'Ko et al., Crystal structure of a supramolecular cluster adduct with cucurbituril, (H3O)(4)[W3S7Cl6](2)(C36N24O12H36)center dot 8H(2)O, RUSS J C CH, 26(7), 2000, pp. 478-481
Citations number
14
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY
ISSN journal
10703284 → ACNP
Volume
26
Issue
7
Year of publication
2000
Pages
478 - 481
Database
ISI
SICI code
1070-3284(200007)26:7<478:CSOASC>2.0.ZU;2-P
Abstract
The crystal structure of (H3O)(4)[W3S7Cl6](2)(C36N24O12H36). 8H(2)O was det ermined. It crystallizes in the monoclinic system with a = 38.687(2), b = 1 8.127(1), c = 12.5760(7) Angstrom, beta = 94.185(1)degrees, space group C2/ c, Z = 4, Pealed = 2.412 g/cm(3). The crystal lattice consists of alternati ng layers of cucurbituril molecules arranged in a parquet fashion and dimer s of cluster anions. A comparison was made with the previously obtained sup ramolecular molybdenum and the tungsten aqua complexes with cucurbituril.