Synthesis and structure of mixed rhenium thioselenochloride triangular clusters

Authors
Rybakov, VB Yanko, OG Aslanov, LA Fokina, ZA Pekhn'yo, VI Volkov, SV
Citation
Vb. Rybakov et al., Synthesis and structure of mixed rhenium thioselenochloride triangular clusters, RUSS J C CH, 26(7), 2000, pp. 482-486
Citations number
11
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY
ISSN journal
10703284 → ACNP
Volume
26
Issue
7
Year of publication
2000
Pages
482 - 486
Database
ISI
SICI code
1070-3284(200007)26:7<482:SASOMR>2.0.ZU;2-I
Abstract
Rhenium compounds Re3S6/5Se0.5Cl7 and Re3S5Se2Cl7 were synthesized by react ing dirhenium heptaoxide with solutions of selenium in sulfur monochloride or sulfur in selenium monochloride upon heating. The compounds were studied by X-ray diffraction analysis. Both structures contain triangular rhenium clusters with disulfide bridges at the triangle sides and a bridging sulfur atom above the Re-3 triangle.