Cleavage of 9-iodo-1,7-carborane with potassium hydroxide in butanol, involving substitution of the iodine atom by a butoxy group and yielding 1-butoxy- and 5-butoxy-nido-7,9-dicarbaundecaborate anions

Authors
Zakharkin, LI Ol'shevskaya, VA Guseva, VV Panfilova, SY
Citation
Li. Zakharkin et al., Cleavage of 9-iodo-1,7-carborane with potassium hydroxide in butanol, involving substitution of the iodine atom by a butoxy group and yielding 1-butoxy- and 5-butoxy-nido-7,9-dicarbaundecaborate anions, RUSS J G CH, 70(1), 2000, pp. 71-72
Citations number
6
Categorie Soggetti
Chemistry
Journal title
RUSSIAN JOURNAL OF GENERAL CHEMISTRY
ISSN journal
10703632 → ACNP
Volume
70
Issue
1
Year of publication
2000
Pages
71 - 72
Database
ISI
SICI code
1070-3632(200001)70:1<71:CO9WPH>2.0.ZU;2-1
Abstract
When heated in butanolic KOH, 9-iodo-1,7-carborane cleaves to stereoisomeri c nido-7,9-di-carbaundecaborate anions. The latter exchange under the react ion conditions their iodine atom for a butoxy group to give 1-butoxy- and 5 -butoxy-nido-7,9-dicarbaundecaborate anions.