Tandem Michael addition-vicarious nucleophilic substitution of hydrogen. Anew access to substituted nitroaromatic compounds.

Authors
Lebars, I Goumont, R Blazejewski, JC Wakselman, C
Citation
I. Lebars et al., Tandem Michael addition-vicarious nucleophilic substitution of hydrogen. Anew access to substituted nitroaromatic compounds., SYN COMMUN, 30(17), 2000, pp. 3161-3166
Citations number
8
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
SYNTHETIC COMMUNICATIONS
ISSN journal
00397911 → ACNP
Volume
30
Issue
17
Year of publication
2000
Pages
3161 - 3166
Database
ISI
SICI code
0039-7911(2000)30:17<3161:TMANSO>2.0.ZU;2-X
Abstract
Michael addition of alkoxides or diethyl methylmalonate to 2-chloroacryloni trile provides functional carbanions which are able to react with 1,3-dinit robenzene following a vicarious nucleophilic substitution to give new subst ituted nitroarenes.