Conjugate addition of zincates derived from ketone alpha,beta-dianions to enones. An access to unsymmetrical 1,6-diketones

Authors
Ryu, I Ikebe, M Sonoda, N Yamato, S Yamamura, G Komatsu, M
Citation
I. Ryu et al., Conjugate addition of zincates derived from ketone alpha,beta-dianions to enones. An access to unsymmetrical 1,6-diketones, TETRAHEDR L, 41(30), 2000, pp. 5689-5692
Citations number
14
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
41
Issue
30
Year of publication
2000
Pages
5689 - 5692
Database
ISI
SICI code
0040-4039(20000722)41:30<5689:CAOZDF>2.0.ZU;2-W
Abstract
The conjugate addition of organozincates derived from ketone alpha,beta-dia nions to enones was examined. Good yields of unsymmetrical 1,6-diketones we re obtained by this reaction. A mixed zincate consisting of the dianion and methyllithium in a 2:1 ratio gave results which were comparable to those o f an unmixed dianion zincate. (C) 2000 Elsevier Science Ltd. All rights res erved.