Palladium(II)-catalyzed regioselective carbonylative coupling of aniline derivatives with terminal aryl acetylenes to give acrylamides under syngas conditions

Citation
B. El Ali et al., Palladium(II)-catalyzed regioselective carbonylative coupling of aniline derivatives with terminal aryl acetylenes to give acrylamides under syngas conditions, TETRAHEDR L, 41(30), 2000, pp. 5761-5764
Citations number
23
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
41
Issue
30
Year of publication
2000
Pages
5761 - 5764
Database
ISI
SICI code
0040-4039(20000722)41:30<5761:PRCCOA>2.0.ZU;2-T
Abstract
The carbonylative coupling of aniline derivatives (la-h) with terminal aryl acetylenes (2a, b) catalyzed by Pd(OAc)(2) and 1,4-bis(diphenylphosphino)b utane (dppb) under syngas conditions affords acrylamide derivatives 3 or 3' in excellent yields and selectivities. (C) 2000 Published by Elsevier Scie nce Ltd.