A novel convergent approach to trans-fused polyether frameworks based on the reaction of vinylstannanes and triflates and its application to a synthetic study of the EFGH ring system of gambierol

Authors
Kadowaki, C Chan, PWH Kadota, I Yamamoto, Y
Citation
C. Kadowaki et al., A novel convergent approach to trans-fused polyether frameworks based on the reaction of vinylstannanes and triflates and its application to a synthetic study of the EFGH ring system of gambierol, TETRAHEDR L, 41(30), 2000, pp. 5769-5772
Citations number
14
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
41
Issue
30
Year of publication
2000
Pages
5769 - 5772
Database
ISI
SICI code
0040-4039(20000722)41:30<5769:ANCATT>2.0.ZU;2-T
Abstract
A new strategy for the convergent assembly of six-membered polycyclic ether ring fragments has been developed based upon the novel reaction between vi nylstannanes with triflates in the presence of a strong base. The applicati on of the present method has allowed for a synthetic study of the EFGH ring of gambierol to be achieved. (C) 2000 Elsevier Science Ltd. All rights res erved.