Citation
G. Cifuentes et al., Kinetics of the electrochemical oxidation of cyanide on PbO2-coated stainless steel, Z METALLKUN, 91(6), 2000, pp. 523-527
Citations number
3
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science",Metallurgy
Journal title
ZEITSCHRIFT FUR METALLKUNDE
ISSN journal
00443093
→ ACNP
Volume
91
Issue
6
Year of publication
2000
Pages
523 - 527
Database
ISI
SICI code
0044-3093(200006)91:6<523:KOTEOO>2.0.ZU;2-G
Abstract
The kinetics of the electrolytic oxidation of cyanide to cyanate on PbO2-co
ated stainless steel anodes has been studied by both experimental and theor
etical means. The anodes were based on 316 stainless steel and performed in
a satisfactory fashion. The studied KCN solutions exhibited a constant pH
= 11 value. Values for all the kinetic parameters have been determined and
a rate law for the studied reaction is proposed.