A. Harata et N. Yamaguchi, Photothermal lensing signal enhancement by the transient absorption of photoexcited states in liquid solutions, ANAL SCI, 16(7), 2000, pp. 743-749
A two-color double-pulse excited photothermal lensing measurement was perfo
rmed to investigate a signal enhancement owing to transient absorption by t
he excited states of solute molecules in liquid solutions. A colinear, mode
-mismatched configuration with a continuous-wave probe laser at 633 nm was
adapted with a focused pump pulse (6.9 ns, 355 nm) and a sequentially incid
ent softly focused second-pump pulse (7.2 ns, 532 nm). The signal-intensity
dependence on the energies of the pump and the second-pump pulses was meas
ured for 1.0 mu M solutions of 2,2'-p-phenylenebis(5-phenyloxazole) in 1-bu
tanol and anthracene in ethanol. A signal enhancement was observed for both
solutions. The signal intensity under certain conditions was one order hig
her than that expected from ground-state absorption. A discussion was made
on determination of the absorption coefficient of the transient species and
on the absorption saturation of the ground and excited states.