Density functional vibrational analysis using wavenumber-linear scale factors

Normal coordinate calculations were performed by the density functional met hod of B3LYP/6-311 + G * * on 205 basic organic and inorganic compounds tak en from the 'Tables of Molecular Vibrational Frequencies' (T. Shimanouchi, 1972). The calculated wavenumbers, nu(calc), of 1729 vibrational modes were correlated with the observed wavenumbers, nu(obs), by a single least-squar es fitting. The relationship obtained, after omitting the vibrational modes that give deviations of more than 10%, is nu(obs)/nu(calc) 1.0087-0.000016 3 (nu(calc)/cm(-1)). The wavenumber-linear scaling method with this relatio nship predicts vibrational wavenumbers with high accuracy and is applicable to any compounds, except for the compounds for which the effect of dispers ion forces is significant. (C) 2000 Elsevier Science B.V. All rights reserv ed.