Batch distillation is an efficient unit operation which allows the separati
on of a multicomponent mixture into its pure constituents in a single colum
n. However, the separation of azeotropic mixtures by distillation is quite
difficult because at the azeotrope the liquid and the gas have the same com
position and, in turn, the driving force for distillation disappears. A sys
tematic presentation of batch distillation processes for the separation of
binary azeotropic mixtures using an entrainer is given.