A. Florez et al., JUDD-OFELT ANALYSIS OF PR3- INFLUENCE OF ODD 3RD-ORDER INTENSITY PARAMETERS( IONS IN FLUOROINDATE GLASSES ), Journal of non-crystalline solids, 213, 1997, pp. 315-320
In this work an analysis of the Judd-Ofelt phenomenological Omega(lamb
da) intensity parameters for the pr(3+) ion in fluoroindate glass is m
ade. Different Pr3+ concentrations, namely 1, 2, 3 and 4 mol% are used
. The experimental oscillator strengths have been determined from the
absorption spectra. A consistent set of parameters is obtained only wi
th the inclusion of odd rank third order intensity parameters and if t
he band at 21470 cm(-1) is assigned to the H-3(4)-->P-3(1) transition
and the I-1(6) component is incorporated in the H-3(4)-->P-3(2) transi
tion at 22 700 cm(-1).