Short-lived radioisotopes are element selectively ionized by the resonance
ionization laser ion source (RILIS) of the on-line isotope separator ISOLDE
(CERN). The relative production of low- and high-spin isomers can be signi
ficantly changed when a narrow-bandwidth laser is used to scan through the
atomic hyperfine structure. This allows the assignment of gamma ray transit
ions to the decay of the individual isomers. Moreover, the measurement of t
he hyperfine splitting provides a very sensitive method for the determinati
on of magnetic moments of exotic isotopes. The technical developments are d
iscussed for the example of copper.