Two compounds containing the cations Mo-2(DPhIP)(4)(n+), n = 1 or 2 and DPh
IP = the anion of 2,6-diphenyliminopiperidine, have been obtained by oxidat
ion of the quadruply-bonded Mo-2(DPhIP)(4) species. The first oxidation pro
cess conserves the structure but results in a slight increase of the Mo-Mo
distance from 2.114(1) to 2.136(2) Angstrom in [Mo-2(DPhIP)(4)](PF6). 2CH(2
)Cl(2) (1.2CH(2)Cl(2)). However, the second oxidation process breaks the di
molybdenum bond, giving a bioctahedral complex, [Mo-2(DPhIP)(4)](BF4)(2). 5
CH(3)CN . Et2O (2.5CH(3)CN . Et2O), with Mo Mo separation of 2.9954(7) Angs
trom. Crystallographic data for 1.2CH(2)Cl(2) are space group C2/c, a = 17.
1891(9) Angstrom, b = 17.807(1) Angstrom, c = 24.210(2) Angstrom, beta = 10
6.403(4)degrees, Z = 4; for 2.5CH(3)CN . Et2O, space group P2(1)/n, a = 16.
523(5) Angstrom, b = 27.418(5) Angstrom, c = 18.163(3) Angstrom, beta = 93.
48(2)degrees, Z = 4.