A one-step synthesis of protected functionalised titanocene dichlorides

Authors
McGowan, MAD McGowan, PC
Citation
Mad. Mcgowan et Pc. Mcgowan, A one-step synthesis of protected functionalised titanocene dichlorides, INORG CH C, 3(7), 2000, pp. 337-340
Citations number
18
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY COMMUNICATIONS
ISSN journal
13877003 → ACNP
Volume
3
Issue
7
Year of publication
2000
Pages
337 - 340
Database
ISI
SICI code
1387-7003(200007)3:7<337:AOSOPF>2.0.ZU;2-G
Abstract
We report a novel, high yield one-step synthesis of water stable and solubl e titanocene dichloride dihydrochloride salts from the direct reaction of t he neutral amino-substituted cyclopentadienes with TiCl4. The following nov el complexes have been synthesised: C5H4(CH2)(2)N(CH (2))(5)](2)TiCl2 (5), [C5H4CH(CH (2))(4)NMe](2)TiCl2, (6), [C5H4(CH (2))(2)N(CH (2))(5)](2)TiCl2 . 2HCl (7), [C5H4CH(CH2)(4)](2)NMeTiCl2 . 2HCl (8), [C5H4(CH2)(2)N(CH2)(5)] (2)TiMe2 (9). (C) 2000 Elsevier Science S.A. All rights reserved.