A novel dimer of oxo-di(acetato)-bridged manganese(III) dimers complex of potential biological significance

Authors
Ruiz, R Sangregorio, C Caneschi, A Rossi, P Gaspar, AB Real, JA Munoz, MC
Citation
R. Ruiz et al., A novel dimer of oxo-di(acetato)-bridged manganese(III) dimers complex of potential biological significance, INORG CH C, 3(7), 2000, pp. 361-367
Citations number
35
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY COMMUNICATIONS
ISSN journal
13877003 → ACNP
Volume
3
Issue
7
Year of publication
2000
Pages
361 - 367
Database
ISI
SICI code
1387-7003(200007)3:7<361:ANDOOM>2.0.ZU;2-B
Abstract
Assembly of the tetranuclear oxomanganese(III) acetato cluster [Mn4O2(O2CMe )(7)(phen)(2)](BF4) from the dinuclear oxo-di(acetato)bridged manganese(III ) species [Mn2O(O2CMe)(2)(H2O)(2)(phen)(2)](BF4)(2) . 3H(2)O in aqueous/ace tic acid MeOH solution occurs via the new 'dimer of dimers' Mn-III complex [Mn2O(O2CMe)(3)(H2O)(phen)(2)](BF4) . MeOH possesing an unprecedent [Mn-4(m u-O)(2)(mu-O2Me)(4) (mu-(OH2O2CMe)-O-...)(2)] core. (C) 2000 Elsevier Scien ce S.A. All rights reserved.