Hydrothermal synthesis and crystal structure of a novel one-dimensional tritungstate: (C2H10N2)[W3O10]

Authors
Yan, BB Xu, Y Goh, NK Chia, LS
Citation
Bb. Yan et al., Hydrothermal synthesis and crystal structure of a novel one-dimensional tritungstate: (C2H10N2)[W3O10], INORG CH C, 3(7), 2000, pp. 379-382
Citations number
16
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY COMMUNICATIONS
ISSN journal
13877003 → ACNP
Volume
3
Issue
7
Year of publication
2000
Pages
379 - 382
Database
ISI
SICI code
1387-7003(200007)3:7<379:HSACSO>2.0.ZU;2-7
Abstract
Ethylenediammonium tritungstate, (C2H10N2)[W3O10], has been hydrothermally synthesized and structurally characterized. The structure of title compound consists of infinite chains running parallel to the b axis, that are made up of distorted WO6 octahedra linked through shared corners and edges. The ethylenediammonium ions occupy interstrand region providing space-filling a nd charge-compensation to anionic tritungstate matrix. (C) 2000 Elsevier Sc ience S.A. All rights reserved.