Isomerism in bis(phenylselenolato) bis(triphenylphosphine) platinum(II): the crystal and molecular structures of cis- and trans-[Pt(SePh)(2)(PPh3)(2)]

Authors
Hannu, MS Oilunkaniemi, R Laitinen, RS Ahlgen, M
Citation
Ms. Hannu et al., Isomerism in bis(phenylselenolato) bis(triphenylphosphine) platinum(II): the crystal and molecular structures of cis- and trans-[Pt(SePh)(2)(PPh3)(2)], INORG CH C, 3(7), 2000, pp. 397-399
Citations number
11
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY COMMUNICATIONS
ISSN journal
13877003 → ACNP
Volume
3
Issue
7
Year of publication
2000
Pages
397 - 399
Database
ISI
SICI code
1387-7003(200007)3:7<397:IIBBPT>2.0.ZU;2-M
Abstract
The reaction of cis-[PtCl2(PPh3)(2)] and NaSePh in benzene produces a mixtu re of cis- and trans-isomers of the monomeric platinum complex [Pt(SePh)(2) (PPh3)(2)]. The low-temperature X-ray structures of both isomers are report ed. The structure of cis-[Pt(SePh)(2)(PPh3)(2)] is the first crystallograph ic characterized cis-isomer of mononuclear platinum(II) complex containing only non-chelating organoselenolato and phosphine ligands. (C) 2000 Elsevie r Science S.A. All rights reserved.