This work studied the thermal conductance of thin layers with randomly orie
nted composites by the percolation theory, and developed an effective-mediu
m approximation (EMA) model for triple bond percolation systems. The result
s showed that the thin layer is anisotropic in conductivities when its thic
kness is lower than the correlation length. The conductivity in normal dire
ction increases with decreasing thickness while the in-plane conductivity d
eclines. The significance of this thickness effect is a function of the con
centration of good conductor and the thermal conductivity ratio of the phas
es in the composites. A threshold concentration exists for the conductivity
of bulk composites, beyond which the effective thermal conductivity increa
ses significantly from that of the poor conductor with increasing concentra
tion.
The developed EMA model agrees quite well with the numerical simulation and
is expected being applicable to predict thermal conductivities of composit
es using the coordination number as a fitting parameter (C) 2000 Elsevier S
cience Ltd. All rights reserved.