Ring opening metathesis polymerization of dicyclopentadiene catalyzed by titanium tetrachloride adduct complexes with nitrogen-containing ligands

Authors
Dono, K Huang, JL Ma, HY Qian, YL
Citation
K. Dono et al., Ring opening metathesis polymerization of dicyclopentadiene catalyzed by titanium tetrachloride adduct complexes with nitrogen-containing ligands, J APPL POLY, 77(14), 2000, pp. 3247-3251
Citations number
24
Categorie Soggetti
Organic Chemistry/Polymer Science","Material Science & Engineering
Journal title
JOURNAL OF APPLIED POLYMER SCIENCE
ISSN journal
00218995 → ACNP
Volume
77
Issue
14
Year of publication
2000
Pages
3247 - 3251
Database
ISI
SICI code
0021-8995(20000929)77:14<3247:ROMPOD>2.0.ZU;2-C
Abstract
Ring opening metathesis polymerization (ROMP) of dicyclopentadiene (DCPD) c atalyzed by titanium tetrachloride adduct complexes such as TiCl4 . 2L [L = pyridine (1), 2-methylpyridine (2), 2,4,6-trimethylpyridine (3), 3-aminopy ridine (4), 2-hyroxypyridine (5)] and CH3Li as cocatalyst was reported. The polymer was characterized by IR and H-1-NMR methods. Five influencing fact ors were also discussed. The catalyst systems TiCl4 . 2L/CH3Li (L = 2-methy lpyridine, 2,4,6-trimethylpyridine) appeared to be very active for the ROMP of DCPD. (C) 2000 John Wiley & Sons, Inc.