A DRAMATIC SHIFT FROM MULTIPLE TO SIMPLE EXCHANGE IN THE CYCLOPENTANED-2 PROBE REACTION ON PALLADIUM CATALYSTS/

Authors
FITZSIMONS G HARDACRE C PATTERSON WR ROONEY JJ CLARKE JKA SMITH MR ORMEROD RM
Citation
G. Fitzsimons et al., A DRAMATIC SHIFT FROM MULTIPLE TO SIMPLE EXCHANGE IN THE CYCLOPENTANED-2 PROBE REACTION ON PALLADIUM CATALYSTS/, Catalysis letters, 45(3-4), 1997, pp. 187-191
Citations number
22
Categorie Soggetti
Chemistry Physical
Journal title
Catalysis letters → ACNP
ISSN journal
1011372X
Volume
45
Issue
3-4
Year of publication
1997
Pages
187 - 191
Database
ISI
SICI code
1011-372X(1997)45:3-4<187:ADSFMT>2.0.ZU;2-X
Abstract
Electron deficient active sites in Pd catalysts, either as films or on supports, are deliberately generated by calcining in O-2 at high temp erature followed by the mildest possible reduction (with the reaction mixture itself), and are manifested by a marked shift from multiple to simple exchange in the cyclopentane/D-2 probe reaction.