CLAY-CATALYZED RADICAL-ADDITION OF ALIPHATIC THIOLS TO STYRENE

Authors
KANNAN P PITCHUMANI K
Citation
P. Kannan et K. Pitchumani, CLAY-CATALYZED RADICAL-ADDITION OF ALIPHATIC THIOLS TO STYRENE, Catalysis letters, 45(3-4), 1997, pp. 271-273
Citations number
22
Categorie Soggetti
Chemistry Physical
Journal title
Catalysis letters → ACNP
ISSN journal
1011372X
Volume
45
Issue
3-4
Year of publication
1997
Pages
271 - 273
Database
ISI
SICI code
1011-372X(1997)45:3-4<271:CROATT>2.0.ZU;2-9
Abstract
When placed in K10-montmorillonite and cation-exchanged clays, alkanet hiols undergo facile anti-Markovnikov addition to styrene by way of a radical mechanism forming sulfides. Surfactant pillared clays are foun d to be remarkably selective by suppressing side reactions.