Kinetics of highly selective catalytic hydrogenation of 2,3,5-trimethylbenzoquinone on Raney nickel catalyst

Citation
S. Mukhopadhyay et al., Kinetics of highly selective catalytic hydrogenation of 2,3,5-trimethylbenzoquinone on Raney nickel catalyst, ORG PROC R, 4(4), 2000, pp. 254-258
Citations number
8
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANIC PROCESS RESEARCH & DEVELOPMENT
ISSN journal
10836160 → ACNP
Volume
4
Issue
4
Year of publication
2000
Pages
254 - 258
Database
ISI
SICI code
1083-6160(200007/08)4:4<254:KOHSCH>2.0.ZU;2-U
Abstract
This work focuses on the catalytic hydrogenation of 2,3,5-trimethylbenzoqui none (TMBQ) to 2,3,5-trimethylhydroquinone (TMHQ), Kinetic interpretation h as been made by studying the important process parameters using Raney nicke l as the catalyst. Thus, at 100% TMBQ conversion level, as high as 100% sel ectivity to TMHQ was accomplished, Experimentation was performed to acquire the most suitable process conditions from the viewpoint of process researc h and development.