The geometric and open path phases of a four-state system subject to time v
arying cyclic potentials are computed from the Schrodinger equation. Fast o
scillations are found in the non-adiabatic case. For parameter values such
that the system possesses degenerate levels, the geometric phase becomes an
omalous, undergoing a sign switch. A physical system to which the results a
pply is a molecular dimer with two interacting electrons. Additionally, the
sudden switching of the geometric phase promises to be an efficient contro
l in two-qubit quantum computing. (C) 2000 Elsevier Science B.V. All rights
reserved.