Synthesis, structural characterisation and electronic behaviour of iron(II) and nickel(II) complexes of N,N-bis(2-pyridylmethyl)aniline

Authors
Hazell, A McKenzie, CJ Nielsen, LP
Citation
A. Hazell et al., Synthesis, structural characterisation and electronic behaviour of iron(II) and nickel(II) complexes of N,N-bis(2-pyridylmethyl)aniline, POLYHEDRON, 19(11), 2000, pp. 1333-1338
Citations number
17
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
POLYHEDRON
ISSN journal
02775387 → ACNP
Volume
19
Issue
11
Year of publication
2000
Pages
1333 - 1338
Database
ISI
SICI code
0277-5387(20000615)19:11<1333:SSCAEB>2.0.ZU;2-5
Abstract
Ni(II) and Fe(II) complexes of the new ligand N,N-bis(2-pyridylmethyl)anili ne (phdpa) of the general formula [M(phdpa)(2)](ClO4)(2) have been prepared and characterised. [Ni(phdpa)(2)](ClO4)(2). 0.5H(2)O was characterised by X-ray crystallography. For comparison, the X-ray structure of [Ni(medpa)(2) ](ClO4)(2) (where medpa is bis(2-pyridylmethyl)methylamine) has been determ ined. The ligand in both [Ni(phdpa)(2)](ClO4)(2) and [Ni(medpa)2](ClO4)(2) exhibit cis-facial geometry. (C) 2000 Elsevier Science Ltd. All rights rese rved.