PbWO1 has recently attracted much attention because of its scintillation ap
plications. We have measured its dielectric response subsequent to Ar+ and
UV irradiation, respectively. Dielectric relaxation was observed, which we
attribute to a complex color center in the WO4-2 tetrahedron. The complex c
olor center in turn led to the distortion of the WO4-2 tetrahedron, which d
egeneracies were removed. was verified by FTIR spectra showing that the nu(
3) and nu(4) degeneracies were removed.