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Photochemistry of arylhydrazides in solution
Authors
Belov, DG
Rogachev, BG
Tkachenko, LI
Smirnov, VA
Aldoshin, SM
Citation
Dg. Belov et al., Photochemistry of arylhydrazides in solution, RUSS CHEM B, 49(4), 2000, pp. 666-668
Citations number
7
Categorie Soggetti
Chemistry
Journal title
RUSSIAN CHEMICAL BULLETIN
ISSN journal
10665285 →
ACNP
Volume
49
Issue
4
Year of publication
2000
Pages
666 - 668
Database
ISI
SICI code
1066-5285(200004)49:4<666:POAIS>2.0.ZU;2-7
Abstract
The photochemical reactions of arylhydrazides ArCONHN=CHR in solution were studied. The main photochemical process was shown to be trans-cis isomeriza tion with a quantum yield of 0.2-0.8 and an activation energy of 21-24 kcal mol(-1).