Samples of intercalated graphite fluoride of the C2F . zR type (R is C6H6)
before and after heating to 150 degrees C in a spectrometer vacuum chamber
were studied by X-ray fluorescence spectroscopy. The C-K alpha differential
spectra of the samples mainly characterizes the electron state of carbon a
toms in the benzene molecule inside the Caf matrix. The differential spectr
um is distinct from the spectrum of solid benzene by additional maxima, whi
ch indicate the interaction between the benzene molecules and the graphite
fluoride matrix. Comparative analysis of the spectrum of the heated sample
and those of graphite and graphite fluoride (CF)(n) suggests thar the layer
s of the C2F matrix contain considerable regions of both completely fluorin
ated and graphite-like regions.