This paper reviews recent progress in structural and electronic characteriz
ations of ultrathin SiO2 thermally grown on Si(100) surfaces and applicatio
ns of such nanometer-thick gate oxides to advanced MOSFETs and quantum-dot
MOS memory devices. Based on an accurate energy band profile determined for
the n(+)-poly-Si/SiO2/Si(100) system, the measured tunnel current through
ultrathin gate oxides has been quantitatively explained by theory. From the
detailed analysis of MOSFET characteristics, the scaling limit of gate oxi
de thickness is found to be 0.8 nm. Novel MOSFETs with a silicon quantum-do
t floating gate embedded in the gate oxide have indicated the multiple-step
electron injection to the dot, being interpreted in terms of Coulombic int
eraction among charged dots. (C) 2000 Academic Press.