Solid solutions of metals such as silver in arsenic trisulfide exhibit a va
riety of interesting characteristics, including the ability to bring che me
tal out of solution by electrodeposition. This allows voltage-controlled sw
itching characteristics to be realized in two terminal devices which may be
fabricated to nanoscale dimensions. In addition, surface electrodeposits m
ay be formed and subsequently broken at grain boundaries to create structur
es that have adjustable current-voltage characteristics at low temperatures
. This paper highlights some initial results of the characterization of nan
oscale structures based on such solid solutions. (C) 2000 Academic Press.