Application of heterogenized oxidation catalysts to reactions of terpenic and other olefins with H2O2

Authors
Sels, BF Villa, AL Hoegaerts, D De Vos, DE Jacobs, PA
Citation
Bf. Sels et al., Application of heterogenized oxidation catalysts to reactions of terpenic and other olefins with H2O2, TOP CATAL, 13(3), 2000, pp. 223-229
Citations number
28
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
TOPICS IN CATALYSIS
ISSN journal
10225528 → ACNP
Volume
13
Issue
3
Year of publication
2000
Pages
223 - 229
Database
ISI
SICI code
1022-5528(2000)13:3<223:AOHOCT>2.0.ZU;2-Q
Abstract
This paper discusses two heterogeneous catalysts that were designed by cova lent or electrostatic immobilization of a homogeneous metal complex. The fi rst material contains Mn-triazacyclononane complexes anchored to silica. Th e second material is a resin with exchanged peroxo W polyoxoanions. Topics of interest include chemoselectivity, regioselectivity and recyclability. T hese aspects are studied in reactions with 18 different olefin substrates, with a focus on terpene reactions.