We present here the passivation mechanism and the chemistry of an (NH4)(2)S
-x-treated Mg-doped GaN surface examined by using x-ray photoelectron spect
roscopy. The native oxide on the GaN surface can be removed by the (NH4)(2)
S-x treatment process. The S atoms not only bond as elemental sulfur and di
sulfides, but occupy nitrogen-related vacancies. (C) 2000 American Institut
e of Physics. [S0003-6951(00)00231-X].