H. Ofuchi et al., Fluorescence EXAFS study on local structures around Mn atoms in MnF2-CaF2 superlattices and double hetero-structures on Si(111), APPL SURF S, 159, 2000, pp. 220-224
Local structures around Mn atoms in MnF2-CaF2 superlattices and double hete
rostructures (DHSs) grown by molecular beam epitaxy (MBE) were investigated
by fluorescence extended X-ray absorption fine structure (EXAFS) measureme
nt. The EXAFS analysis revealed that in thin MnF2 layers (less than or equa
l to 3 ML) fluorite structure that does not exist at normal conditions prev
ailed over the rutile structure, and the content ratio of the fluorite MnF2
strongly depended on the thickness of the MnF2 lever. Therefore, the thin
MnF2 layers grew in fluorite structure on CaF2 and changed to the rutile st
ructure with the increase Uf the MnF2 layer thickness. (C) 2000 Elsevier Sc
ience B.V. All rights reserved.