A new technique namely chemical bonding by surface modification (CBSM) has
been developed to bond GaAs thin films on Si substrate. The bonded GaAs epi
layer, detached from its orginal substrate in conjunction with epitaxial li
ft-off (ELO) process, possessed smooth surface morphology and exhibited uni
form bonding across the interface. The X-ray full width at half maximum (FW
HM) of 16 are-sec from double crystal X-ray diffraction (DCD) and no peak w
avelength shift from photoluminscence (PL) measurements reflected the high
crystalline quality of the bonded films. The depth profile by XPS revealed
at the interface the occurrence of surface modification. The surface modifi
cation resulted in the formation of Ga2Se3 and SiS2, which attributed for t
he strong and high quality bonding between GaAs and Si. (C) 2000 Elsevier S
cience B.V. All rights reserved.