A search was conducted using the Hubble Space Telescope (HST) Goddard High
Resolution Spectrograph (GHRS) in 1994 August for Iogenic H Ly alpha emissi
on predicted from electron capture by precipitating trapped magnetospheric
protons. The Doppler-shifted diffusely reflected solar Lya component was de
tected in the combined high-resolution spectra, partly resolved from the ge
ocoronal emission. This component had a disk-averaged intensity of 2.5 +/-
0.7 kR. Io's corresponding geometric albedo in this line, which must includ
e the effects of atmospheric SO2 absorption, was 0.055 +/- 0.015. Iogenic e
mission from ambient H atoms was probably also detected, with a disk-averag
ed intensity greater than 280 R, most likely approximate to 485 R, which su
ggests a significant column of atmospheric or coronal H. The dominant brigh
tness of the reflected solar line in our GHRS data supports the proposed hy
pothesis that the primary source of Io's H Ly alpha emission observed more
recently (1997-1998) by the HST Space Telescope Imaging Spectrograph at low
spectral resolution is diffusely reflected sunlight, rather than Iogenic H
. The consequence is a significant increase in the absorbing SO2 column of
Io's trailing atmosphere as Jupiter moved 0.37-0.44 AU closer to the Sun; t
his could result from the higher SO2 equilibrium vapor pressure over the 4-
5 K warmer ice. Averaging low-resolution HST GHRS archival far-ultraviolet
spectra of Io obtained during 1994-1996 provided a 2 sigma upper limit of 5
.2 R Angstrom(-1) for the disk-averaged intensity of Ly alpha emission from
energetic (27-223 keV) precipitating protons. This corresponds to an estim
ated upper limit of 47 R, integrated over the red Doppler wing of the therm
al distribution for protons of mean energy 30-60 keV. This is close to esti
mates for a proton aurora generated in the SO2 column of Io's trailing atmo
sphere, indicating that SO2 may be Io's dominant atmospheric gas. A 2 sigma
upper limit of 123 R per line is derived for nearby fluorescence of extrem
e-UV radiation by ambient atmospheric sulfur.