The linear viscoelastic properties of one family of base asphalts, unmodifi
ed or modified by the simple addition of an elastomer or by further in-situ
crosslinking, have been investigated. The time-temperature superposition p
rinciple was shown to be valid for the base as well as for the modified asp
halts. The addition of the elastomer styrene-butadiene (SB) copolymer incre
ased drastically the storage modulus and the elastic character of the aspha
lts. The thermal susceptibility of the polymer modified asphalts was consid
erably reduced and this combined with an increased resistance to deformatio
n (larger complex modulus) suggests much better performances for road appli
cations. The chemically modified asphalt containing 3% SB showed similar vi
scoelastic properties as the physical blend containing 6% SB.