Reaction of aromatic radical cations with RuCl3 center dot 3H(2)O

Authors
Michman, M Oron, M Schaefer, HJ
Citation
M. Michman et al., Reaction of aromatic radical cations with RuCl3 center dot 3H(2)O, COLL CZECH, 65(6), 2000, pp. 924-940
Citations number
28
Categorie Soggetti
Chemistry
Journal title
COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS
ISSN journal
00100765 → ACNP
Volume
65
Issue
6
Year of publication
2000
Pages
924 - 940
Database
ISI
SICI code
0010-0765(200006)65:6<924:ROARCW>2.0.ZU;2-1
Abstract
Interactions of RuCl3. 3H(2)O with radical cations of aromatic ethers, 1,4- di-tert-butyl-2,5-dimethoxybenzene, 3,5-di-tert-butyl-1,2-dimethoxybenzene and 2-tert-butyl-1,4-dimethoxybenzene, and with aromatic amines, 2,4,6-tri- tert-butylaniline and N,N,N',N'-tetramethyl-1,4-phenylenediamine, were obse rved by voltammetry. ESR and UV spectroscopies were used for the study of t he the first two ethers. The effect of RuCl3. 3H(2)O was also examined by c ontrolled potential electrolysis.