Citation
M. Somei et F. Yamada, The first and simple total synthesis of cappariloside A(1), HETEROCYCLE, 53(7), 2000, pp. 1573-1578
Citations number
20
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
HETEROCYCLES
ISSN journal
03855414
→ ACNP
Volume
53
Issue
7
Year of publication
2000
Pages
1573 - 1578
Database
ISI
SICI code
0385-5414(20000701)53:7<1573:TFASTS>2.0.ZU;2-9
Abstract
A lithium hydroxide promoted simple glycosylation of 4-hydroxyindole-3-acet
onitrile with 2,3,4, 6-tetra-O-acetyl-alpha-D-glucopyranosyl bromide was de
veloped. Utilizing the method, the first and five steps total synthesis of
cappariloside A was achieved from indole-3-carbaldehyde in 41% overall yiel
d.