Characterization, luminescence and crystal structure of uranyl nitrate complexes with diphenyl-N-ethylphosphine amide and tripiperidinephosphine oxide

Authors
de Aquino, AR Bombieri, G Isolani, PC Vicentini, G Zukerman-Schpector, J
Citation
Ar. De Aquino et al., Characterization, luminescence and crystal structure of uranyl nitrate complexes with diphenyl-N-ethylphosphine amide and tripiperidinephosphine oxide, INORG CHIM, 306(1), 2000, pp. 101-105
Citations number
28
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANICA CHIMICA ACTA
ISSN journal
00201693 → ACNP
Volume
306
Issue
1
Year of publication
2000
Pages
101 - 105
Database
ISI
SICI code
0020-1693(20000811)306:1<101:CLACSO>2.0.ZU;2-W
Abstract
The uranyl complexes UO2(NO3)(2)L-2 (L = DPEPA (1) diphenyl-N,N-ethylphosph ine amide and TPPPO (2) tripiperidine oxide) have been prepared. Spectrosco pic studies indicate that L is bound to the uranyl group via the phosphoryl oxygen atom. The crystal structures of (1) and (2) show a hexagonal-bipyra midal coordination about uranium. The luminescence properties of the compou nds have been also investigated. (C) 2000 Elsevier Science S.A. All rights reserved.