Copper complexes with multidentate ligands derived from L-proline. X-ray crystal structure of {[Cu(N,N '-bis[(S)-prolyl]ethylenediamine)]ClO4}(2)center dot(MeCN)(2)

The reaction of [Cu(CH3CN)(4)]X (X = ClO4, PF6) with multidentate ligands N ,N'-bis[(S)-prolyl]ethylenediamine (1), N,N'-bis[(S)-N-benzylprolyl]ethylen ediamine (2), N,N'-bis {[(S)-pyrrolidin-2-yl]methyl}ethylenediamine (3), N, N'-bis-{[(S)-N-benzylpyrrolidin-2-yl]methyl}ethylenediamine (4) gives coppe r complexes which were characterised by analytical (elemental analysis, and mass spectroscopy) and FT IR, NMR and electronic spectroscopies. The {[Cu( N,N'-bis[(S)-prolyl]ethylenediamine)]-ClO4}(2).(MeCN)(2) complex was charac terised by X-ray crystallography. This new family of Cu-complexes catalyse the cyclopropanation of styrene with ethyl and t-butyl diazoacetate to yiel d cis/trans 2-phenylcyclopropan-1-carboxylates in good yields and selectivi ty against dimerisation and low ee (<10%). (C) 2000 Elsevier Science S.A. A ll rights reserved.