Hh. Deng et al., THE SURFACE CAPPING OF THE CDS NANOPARTICLE WITH THE ELECTRONEUTRAL GROUP OF 2,2'-BIPYRIDINE IN AOT REVERSE MICELLE, Chemistry Letters, (6), 1997, pp. 483-484
The CdS nanoparticles capped with 2,2'-bipyridine (bpy) had been synth
esized in AOT reverse micelle. Bpy molecules adsorb on the Cd2+-rich s
urface of the CdS cluster via the nitrogen sigma donation, which was e
lucidated by the FT-Raman spectroscopy. AOT exists as an anion ion of
AOTSO(3)(-) in the CdS/bpy composite.