ORGANOALUMINUM-PROMOTED REARRANGEMENT OF EPOXYSILANES TO ALPHA-SILYLALDEHYDES

Authors
OOI T KIBA T MARUOKA K
Citation
T. Ooi et al., ORGANOALUMINUM-PROMOTED REARRANGEMENT OF EPOXYSILANES TO ALPHA-SILYLALDEHYDES, Chemistry Letters, (6), 1997, pp. 519-520
Citations number
16
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
6
Year of publication
1997
Pages
519 - 520
Database
ISI
SICI code
0366-7022(1997):6<519:OROETA>2.0.ZU;2-P
Abstract
Selective rearrangement of epoxysilanes to alpha-silylaldehydes has be en achieved with high efficiency by using exceptionally bulky oxygenop hilic methylaluminum bis(4-bromo-2,6-di-tert-butylphenoxide) (MABR) as a stoichiometric reagent. Ctalytic use of MABR led to silyl enol ethe rs in good yield.