THE RING-OPENING REACTION OF 3,3,3-TRIFLUOROPROPENE OXIDE WITH CARBANIONS - REACTION OF ALPHA-CYANOCARBANIONS

Authors
KATAGIRI T AKIZUKI M KURIYAMA T SHINKE S UNEYAMA K
Citation
T. Katagiri et al., THE RING-OPENING REACTION OF 3,3,3-TRIFLUOROPROPENE OXIDE WITH CARBANIONS - REACTION OF ALPHA-CYANOCARBANIONS, Chemistry Letters, (6), 1997, pp. 549-550
Citations number
13
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
6
Year of publication
1997
Pages
549 - 550
Database
ISI
SICI code
0366-7022(1997):6<549:TRRO3O>2.0.ZU;2-#
Abstract
Nucleophilic ring-opening reaction of 3,3,3-trifluoropropene oxide (TF PO) was studied. Reaction of TFPO with carbanions stabilized by cyano group gave gamma-cyanohydrins in moderate to good yields. Meanwhile, r eaction of the carbanions from malonic ester and nitromethane resulted in recovery of TFPO.