OXIDATION MECHANISM OF NAD DIMER MODEL COMPOUNDS

Authors
PATZ M KUWAHARA Y SUENOBU T FUKUZUMI S
Citation
M. Patz et al., OXIDATION MECHANISM OF NAD DIMER MODEL COMPOUNDS, Chemistry Letters, (6), 1997, pp. 567-568
Citations number
12
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
6
Year of publication
1997
Pages
567 - 568
Database
ISI
SICI code
0366-7022(1997):6<567:OMONDM>2.0.ZU;2-H
Abstract
The oxidation of a dimeric N-benzyldihydronicotinamide with various ox idants such as quinones, triphenyl carbenium ions and a triplet exited tris(bipyridine) ruthenium(rr) complex occurs via initial outer-spher e electron transfer followed by fast C-C bond cleavage and second elec tron transfer. The kinetic studies allow the determination of the oxid ation potential of this compound.