In this study, the removals of the mercury and methylmercury by applying an
electric field have been investigated. The experimental results show that
the non-uniform distributions of the pH, conductivity and potential gradien
t would be formed during the treatment. These unexpected distributions woul
d slow down the removal ofcontaminants. So the mercury and methylmercury co
uld be only reduced to about 73.6% and 59.4% after 100-day treatment, respe
ctively. Thus, the enhancement by using buffer solutions or cation exchange
membranes was conducted to avoid the back-migration of the OH- generated a
t the cathode. The results show that the removal efficiencies of the mercur
y could attain 88% or more and that of the methylmercury could reach to 94%
or more after only 60-day treatments by using either buffer solutions or c
ation exchange membranes.