Gk. Varier et al., INVESTIGATIONS ON NANOSECOND LASER-PRODUCED PLASMA IN AIR FROM THE MULTICOMPONENT MATERIAL YBA2CU3O7, Spectrochimica acta, Part B: Atomic spectroscopy, 52(5), 1997, pp. 657-666
The laser produced plasma from the multi-component target YBa2Cu3O7 wa
s analyzed using Michelson interferometry and time resolved emission s
pectroscopy. The interaction of 10 ns pulses of 1.06 mu m radiation fr
om a Q-switched Nd:YAG laser at laser power densities ranging from 0.5
5 GW cm(-2) to 1.5 GW cm(-2) has been studied. Time resolved spectral
measurements of the plasma evolution show distinct features at differe
nt points in its temporal history. For a time duration of less than 55
ns after the laser pulse (for a typical laser power density of 0.8 GW
cm(-2)), the emission spectrum is dominated by black-body radiation.
During cooling after 55 ns the spectral emission consists mainly of ne
utral and ionic species. Line averaged electron densities were deduced
from interferometric line intensity measurements at various laser pow
er densities. Plasma electron densities are of the order of 10(17) cm(
-3) and the plasma temperature at the core region is about 1 eV. The m
easurement of plasma emission line intensities of various ions inside
the plasma gave evidence of multiphoton ionization of the elements con
stituting the target at low laser power densities. At higher laser pow
er densities the ionization mechanism is collision dominated. For elem
ents such as nitrogen present outside the target, ionization is due to
collisions only. (C) 1997 Elsevier Science B.V.